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All times are CEST (UTC + 2)
| Liverpool – Southampton | 0:0 (end) | | | Arsenal – Man Utd. | 2:0 (end) |
| Alavés – Bilbao | 1:0 (end) | | | Valencia – Osasuna | 4:1 (end) | | | La Coruňa – Espanyol | 1:2 (end) |
| Malaga – Celta Vigo | 3:0 (end) |
| Hamburg – Mohuč | 0:0 (end) | | | Freiburg – Schalke | 2:0 (end) |
| Ajax – GA Eagles | 4:0 (end) | | | Excelsior – Feyenoord | 3:0 (end) | | | Groningen – Eindhoven | 1:1 (end) |
| Kerkrade – Willem II | 1:0 (end) | | | Utrecht – Arnhem | 1:0 (end) | | | Heracles – Den Haag | 4:0 (end) |
| Nijmegen – Alkmaar | 2:1 (end) | | | Zwolle – Heerenveen | 2:1 (end) | | | Sparta Rotterdam – Twente | 1:0 (end) |
| Oostende – Gent | 4:3 (end) | | | Anderlecht – Waregem | 2:0 (end) | | | Genk – Eupen | 2:1 (end) |
| Sporting – Belenenses | 1:3 (end) | | | Tondela – Setúbal | 2:1 (end) | | | Guimarães – Arouca | 1:0 (end) |
| Rio Ave – SL Benfica | 0:1 (end) |
| Rheindorf Altach – Austria | 1:1 (end) |
| Orenburg – FK Krasnodar | 1:0 (end) | | | Kazaň – Ufa | 2:1 (end) | | | FC Zenit – Grozny | 0:1 (end) |
| Brno – Zlín | 2:0 (end) | | | Sparta – Liberec | 1:0 (end) | | | Hradec Králové – Teplice | 0:2 (end) |
| Mladá Boleslav – Jihlava | 3:1 (end) |
| Trenčín – Trnava | 3:4 (end) | | | Zlaté Moravce – Dunajská Streda | 1:2 (end) |
Goals:
22. Garay (Nani), 45. Garay (Zaza), 70. Zaza (Rodrigo), 74. Rodrigo – 90+2. Olavide (Berenguer)
Ball possession: 63 % : 37 %.
Shots on target: 9:4. Shots off target: 8:4. Corners: 9:2. Offsides: 2:1. Fouls: 15:11.
Referees:
Attendance:
Cards: 64. Zaza (VAL) – 47. D. García (OSS), 78. Berenguer (OSS)
Penalty missed:
Ball possession: 63 % : 37 %.
Shots on target: 9:4. Shots off target: 8:4. Corners: 9:2. Offsides: 2:1. Fouls: 15:11.
Valencia CF:
Doménech – Montoya, Garay, Mangala, Gayá (79. S. Mina) – Parejo (69. Rodrigo), E. Pérez – Cancelo, Soler (79. Medrán), Nani – Zaza.
Subs: Diego Alves – Munir, Medrán, S. Mina, Rodrigo, Orellana, Santos.
Coach:
CA Osasuna: Sirigu – Buñuel (73. J. Flaño), D. García, Vujadinović, Fuentes – Berenguer, Čaušić, Fausto (33. De las Cuevas) – R. Torres, O. Riera, León (79. Olavide).
Subs: N. Pérez – C. Clerc, De las Cuevas, J. Flaño, Mondragón Dosman, Romero, Olavide.
Coach:
Subs: Diego Alves – Munir, Medrán, S. Mina, Rodrigo, Orellana, Santos.
Coach:
CA Osasuna: Sirigu – Buñuel (73. J. Flaño), D. García, Vujadinović, Fuentes – Berenguer, Čaušić, Fausto (33. De las Cuevas) – R. Torres, O. Riera, León (79. Olavide).
Subs: N. Pérez – C. Clerc, De las Cuevas, J. Flaño, Mondragón Dosman, Romero, Olavide.
Coach:
Referees:
Attendance:
Scorer is MIGUEL OLAVIDE. Assisted by Alex Berenguer.
Valencia CF substitution: Carlos Soler is replaced by Álvaro Medrán.
CA Osasuna substitution: Sergio León is replaced by Miguel Olavide.
Scorer is RODRIGO.
Scorer is SIMONE ZAZA. Assisted by Rodrigo.
Scorer is EZEQUIEL GARAY. Assisted by Simone Zaza.
Scorer is EZEQUIEL GARAY. Assisted by Nani.