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All times are CEST (UTC + 2)
| Arsenal – Tottenham | 1:1 (end) | | | Hull City – Southampton | 2:1 (end) | | | Liverpool – Watford | 6:1 (end) |
| Swansea – Man Utd. | 1:3 (end) | | | Leicester – West Brom | 1:2 (end) |
| Real – Leganés | 3:0 (end) | | | Espanyol – Bilbao | 0:0 (end) | | | Celta Vigo – Valencia | 2:1 (end) |
| Villarreal – Betis | 2:0 (end) | | | Sevilla – Barcelona | 1:2 (end) |
| RB Leipzig – Mohuč | 3:1 (end) | | | Schalke – Bremen | 3:1 (end) |
| Utrecht – Excelsior | 2:1 (end) | | | Alkmaar – Ajax | 2:2 (end) | | | Arnhem – Heracles | 1:2 (end) |
| GA Eagles – Feyenoord | 1:0 (end) |
| Club Bruggy – Genk | 1:1 (end) | | | Anderlecht – Oostende | 1:1 (end) | | | Standard – Mouscron | 2:1 (end) |
| Gent – Waasland-Beveren | 2:0 (end) |
| Moreirense – Setúbal | 1:2 (end) | | | Porto – SL Benfica | 1:1 (end) | | | Sporting – Arouca | 3:0 (end) |
| Marítimo – Braga | 1:0 (end) |
| Rapid – Wolfsberger | 0:1 (end) | | | Rheindorf Altach – Austria | 5:1 (end) | | | Mattersburg – Salzburg | 2:1 (end) |
| Rostov – Arsenal Tula | 4:1 (end) | | | Grozny – FC Zenit | 2:1 (end) | | | CSKA Moskva – Perm | 2:2 (end) |
| FK Krasnodar – Orenburg | 3:3 (end) |
| Liberec – Sparta | 0:0 (end) | | | Karviná – Slovácko | 0:1 (end) | | | Plzeň – Jablonec | 3:1 (end) |
| Slovan Bratislava – Dunajská Streda | 1:0 (end) | | | Žilina – Trnava | 7:0 (end) |
Goals:
23. Trigueros (B. Soriano), 54. R. Soriano (J. Costa)
Ball possession: 49 % : 51 %.
Shots on target: 7:3. Shots off target: 3:4. Corners: 10:1. Offsides: 2:1. Fouls: 16:12.
Referees: Inaki Vicandi Garrido
Attendance:
Cards: 72. Cejudo (RBE), 79. Martin (RBE)
Penalty missed:
Ball possession: 49 % : 51 %.
Shots on target: 7:3. Shots off target: 3:4. Corners: 10:1. Offsides: 2:1. Fouls: 16:12.
Villarreal CF:
Asenjo – M. Gaspar, Musacchio, V. Ruiz, J. Costa – R. Soriano (74. Čeryšev), Trigueros, B. Soriano, Castillejo (79. Hernández Cascante) – Bakambu (67. J. dos Santos), N. Sansone.
Subs: Andrés Fernández – Álvaro González, J. dos Santos, Hernández Cascante, Čeryšev, Pato, Antonio Rukavina.
Coach:
Real Betis: Adán – Piccini, Pezzella, Mandi, Á. Martínez – Cejudo, Petros, Martin, Gutiérrez (57. Rubén Castro) – A. Sanabria (57. Nahuel), Joaquín (56. Alegría).
Subs: D. Giménez – Alegría, Brašanac, Rubén Castro, Donk, Nahuel, R. Navarro.
Coach:
Subs: Andrés Fernández – Álvaro González, J. dos Santos, Hernández Cascante, Čeryšev, Pato, Antonio Rukavina.
Coach:
Real Betis: Adán – Piccini, Pezzella, Mandi, Á. Martínez – Cejudo, Petros, Martin, Gutiérrez (57. Rubén Castro) – A. Sanabria (57. Nahuel), Joaquín (56. Alegría).
Subs: D. Giménez – Alegría, Brašanac, Rubén Castro, Donk, Nahuel, R. Navarro.
Coach:
Referees: Inaki Vicandi Garrido
Attendance:
Scorer is ROBERTO SORIANO. Assisted by Jaume Costa.
Scorer is MANU TRIGUEROS. Assisted by Bruno Soriano.