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| Liverpool – Burnley | 2:1 (end) |
| Real Sociedad – Bilbao | 0:2 (end) | | | La Coruňa – Barcelona | 2:1 (end) | | | Celta Vigo – Villarreal | 0:1 (end) |
| Real – Betis | 2:1 (end) |
| Schalke – Augsburg | 3:0 (end) | | | Hamburg – Mönchengladbach | 2:1 (end) |
| Willem II – Zwolle | 2:0 (end) | | | Feyenoord – Alkmaar | 5:2 (end) | | | Kerkrade – Groningen | 3:1 (end) |
| Ajax – Twente | 3:0 (end) |
| Club Bruggy – Sint-Truiden | 2:2 (end) | | | Anderlecht – Waasland-Beveren | 3:0 (end) | | | Standard – Oostende | 2:2 (end) |
| Gent – Mechelen | 3:0 (end) | | | Kortrijk – Mouscron | 0:2 (end) | | | Eupen – Waregem | 1:3 (end) |
| Lokeren – Charleroi | 0:0 (end) | | | Westerlo – Genk | 0:4 (end) |
| Boavista – Marítimo | 3:0 (end) | | | Rio Ave – Moreirense | 3:2 (end) | | | Guimarães – Estoril | 3:3 (end) |
| Sturm Graz – Rapid | 2:1 (end) |
| Perm – FC Zenit | 1:0 (end) | | | Spartak – Machačkala | 1:0 (end) | | | Rostov – Grozny | 0:0 (end) |
| Mladá Boleslav – Sparta | 1:0 (end) | | | Slavia – Teplice | 2:1 (end) |
| Trenčín – Michalovce | 4:1 (end) | | | Podbrezová – Trnava | 0:1 (end) |
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90+1
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Théo Bongonda (Real Club Celta de Vigo) is shown a yellow card.
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90
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Iago Aspas (Real Club Celta de Vigo) is shown a yellow card.
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90
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Carles Planas (Real Club Celta de Vigo) is shown a yellow card.
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87
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Mateo Musacchio (Villarreal CF) is shown a yellow card.
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85
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Jonathan dos Santos (Villarreal CF) is shown a yellow card.
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73
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Jaume Costa (Villarreal CF) is shown a yellow card.
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72
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Andrés Fernández (Villarreal CF) is shown a yellow card.
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14
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Hugo Mallo (Real Club Celta de Vigo) is shown a yellow card.
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8
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Roberto Soldado (Villarreal CF) is shown a yellow card.
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Goals:
45. R. Soriano (Musacchio)
Referees: López – Zapatero, Cimiano
Attendance:
Cards: 14. Mallo (CVG), 90. Planas (CVG), 90. Aspas (CVG), 90+1. Bongonda (CVG) – 8. Soldado (VLR), 72. Andrés Fernández (VLR), 73. J. Costa (VLR), 85. J. dos Santos (VLR), 87. Musacchio (VLR)
Penalty missed:
Celta de Vigo:
S. Álvarez – Mallo, Sergi Gómez (82. Wass), Roncaglia, Planas – Radoja (69. Aspas), Díaz – Hjulsager (59. Beauvue), Jozabed, Bongonda – Rossi.
Subs: Villar – Cheikh Diop, Aspas, Beauvue, Wass, Cabral, Señé.
Coach:
Villarreal CF: Andrés Fernández – M. Gaspar, Musacchio, V. Ruiz, J. Costa – J. dos Santos, B. Soriano, Trigueros, R. Soriano (89. Hernández Cascante) – Bakambu (81. Castillejo), Soldado (71. N. Sansone).
Subs: Barbosa – Álvaro González, Hernández Cascante, N. Sansone, Castillejo, Antonio Rukavina, Borré.
Coach:
Subs: Villar – Cheikh Diop, Aspas, Beauvue, Wass, Cabral, Señé.
Coach:
Villarreal CF: Andrés Fernández – M. Gaspar, Musacchio, V. Ruiz, J. Costa – J. dos Santos, B. Soriano, Trigueros, R. Soriano (89. Hernández Cascante) – Bakambu (81. Castillejo), Soldado (71. N. Sansone).
Subs: Barbosa – Álvaro González, Hernández Cascante, N. Sansone, Castillejo, Antonio Rukavina, Borré.
Coach:
Referees: López – Zapatero, Cimiano
Attendance: