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| West Ham – Southampton | 0:3 (end) |
| Leganés – Valencia | 1:2 (end) | | | Atlético – La Coruňa | 1:0 (end) | | | Villarreal – Osasuna | 3:1 (end) |
| Espanyol – Celta Vigo | 0:2 (end) |
| Hoffenheim – Schalke | 2:1 (end) | | | Kolín nad Rýnem – RB Leipzig | 1:1 (end) |
| Nijmegen – Willem II | 0:0 (end) | | | Utrecht – Sparta Rotterdam | 2:0 (end) | | | Twente – Arnhem | 2:1 (end) |
| Feyenoord – Kerkrade | 5:0 (end) |
| Standard – Eupen | 3:0 (end) | | | Kortrijk – Genk | 4:1 (end) | | | Anderlecht – Westerlo | 1:2 (end) |
| Braga – Setúbal | 2:1 (end) | | | Marítimo – Tondela | 2:0 (end) | | | FC Ferreira – Rio Ave | 2:1 (end) |
| Moreirense – Guimarães | 0:1 (end) |
| Rheindorf Altach – Salzburg | 0:0 (end) |
| Orenburg – Ural | 0:1 (end) | | | Arsenal Tula – Grozny | 0:0 (end) | | | Spartak – Ufa | 0:1 (end) |
| Machačkala – FC Zenit | 2:2 (end) |
| Sparta – Slavia | 0:2 (end) |
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63
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Miguel Olavide (CA Osasuna) is shown a yellow card.
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24
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Mario Fernández (CA Osasuna) is shown a yellow card.
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Goals:
5. Pato (Castillejo), 24. B. Soriano (pen.), 39. N. Sansone (Castillejo) – 45+1. R. Torres
Ball possession: 59 % : 41 %.
Shots on target: 5:3. Shots off target: 5:6. Corners: 5:5. Offsides: 5:1. Fouls: 7:17.
Referees: Ocón – C. García, Matías
Attendance:
Cards: 24. Fernández (OSS), 63. Olavide (OSS)
Penalty missed:
Ball possession: 59 % : 41 %.
Shots on target: 5:3. Shots off target: 5:6. Corners: 5:5. Offsides: 5:1. Fouls: 7:17.
Villarreal CF:
Asenjo – M. Gaspar, Álvaro González, V. Ruiz, J. Costa – Castillejo, Trigueros, B. Soriano, R. Soriano (74. Čeryšev) – N. Sansone (79. Borré), Pato (63. J. dos Santos).
Subs: Andrés Fernández – Antonio Rukavina, N'Diaye, Borré, J. dos Santos, Bonera, Čeryšev.
Coach:
CA Osasuna: Fernández (46. Fernández) – Fuentes, Oier, D. García, Bonnin, C. Clerc (46. Romero) – Mérida (54. Olavide), M. Flaño, R. Torres – León, Rivière.
Subs: Fernández – Buñuel, Olavide, O. Riera, Romero, U. García, Álamo.
Coach:
Subs: Andrés Fernández – Antonio Rukavina, N'Diaye, Borré, J. dos Santos, Bonera, Čeryšev.
Coach:
CA Osasuna: Fernández (46. Fernández) – Fuentes, Oier, D. García, Bonnin, C. Clerc (46. Romero) – Mérida (54. Olavide), M. Flaño, R. Torres – León, Rivière.
Subs: Fernández – Buñuel, Olavide, O. Riera, Romero, U. García, Álamo.
Coach:
Referees: Ocón – C. García, Matías
Attendance: